An integrated approach combining magnetic, geochemical and particle-based techniques to assess metal(loid) loadings in urban venues frequented by children

Urban venues frequented by children, such as playgrounds, are potentially important sources of exposure to anthropogenic metal(loids). Environmental quality of outdoor playgrounds is mainly assessed through direct geochemical monitoring, which is time-consuming and expensive. In this study we adapted a multidisciplinary approach combining magnetic measurements, geochemical analyses, particle-based techniques and bioaccessibility data so as to evaluate the applicability of magnetic methods as a low-cost and easy-to-use technology to monitor pollution level in public playgrounds. Playground sands were collected and their magnetic characteristics were studied in detail aiming to gain helpful additional details in relation to the type, concentration and particle-size distribution of the sand-bound magnetic particles. The obtained χ_lf values indicated an enhanced level of sand-bound magnetic components, while the dominant control of SSD grains on the magnetic load of playground-PG sands was revealed. Hysteresis parameters and thermomagnetic curves indicated low-coercivity ferrimagnetic minerals, such as magnetite and/or maghemite, as the predominant magnetic carriers. Ratios of χ_ARM/χ_lf and χ_ARM/SIRM indicated the dominance of coarser anthropogenic magnetic grains in the sampled PG sands compared to other recreational areas. Correlation analysis among magnetic variables and reported metal(loid) contents designated χ_ARM as a more effective indicator for the detection of anthropogenic load in PG sand samples than χ_lf or SIRM. Simultaneously, through geochemical analyses in magnetic extracts separated from PG sands, metal(loid) contents were notably enriched in the magnetic fraction validating their strong affinity with sand-bound magnetic particles. Finally, bioaccessibility tests revealed lower UBM-extracted fractions for the magnetic extracts of PG sands compared to bulk samples. However, arsenic (As) was more bioaccessible in the sand-bound magnetic particles raising serious concerns for the children exposed to playground sands.