In Situ Tumor Vaccination with Calcium-Linked Degradable Coacervate Nanocomplex Co-Delivering Photosensitizer and TLR7/8 Agonist to Trigger Effective Anti-Tumor Immune Responses

Adv Healthc Mater. 2022 Jun;11(12):e2102781. doi: 10.1002/adhm.202102781. Epub 2022 Mar 24.

Abstract

In situ anti-tumor vaccination is an attractive type of cancer immunotherapy which relies on the effectiveness of dendritic cells (DCs) to engulf tumor antigens, become activated, and present antigens to T cells in lymphoid tissue. Here, a multifunctional nanocomplex based on calcium crosslinked polyaspartic acid conjugated to either a toll-like receptor (TLR)7/8 agonist or a photosensitizer is reported. Intratumoral administration of the nanocomplex followed by laser irradiation induces cell killing and hence generation of a pool of tumor-associated antigens, with concomitant promotion of DCs maturation and expansion of T cells in tumor-draining lymph nodes. Suppression of tumor growth is observed both at the primary site and at the distal site, thereby hinting at successful induction of an adaptive anti-tumor response. This strategy holds promise for therapeutic application in a pre-operative and post-operative setting to leverage to mutanome of the patient's own tumor to mount immunological memory to clear residual tumor cells and metastasis.

Keywords: anti-tumor immunity; in situ cancer vaccination; phototherapy; polymer conjugates; toll-like receptor 7/8 agonists.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adjuvants, Immunologic / therapeutic use
  • Animals
  • Antigens, Neoplasm
  • Calcium
  • Cancer Vaccines* / administration & dosage
  • Dendritic Cells
  • Drug Delivery Systems
  • Immunity
  • Male
  • Mice
  • Mice, Inbred BALB C
  • Mice, Inbred C57BL
  • Nanoparticles
  • Neoplasms* / drug therapy
  • Photosensitizing Agents / pharmacology
  • Photosensitizing Agents / therapeutic use
  • Toll-Like Receptor 7* / agonists
  • Toll-Like Receptor 8* / agonists
  • Vaccination

Substances

  • Adjuvants, Immunologic
  • Antigens, Neoplasm
  • Cancer Vaccines
  • Photosensitizing Agents
  • TLR7 protein, human
  • Toll-Like Receptor 7
  • Toll-Like Receptor 8
  • Calcium