Polycyclic aromatic hydrocarbons (PAHs) in gas, PM_2.5, and frost samples in a severely polluted rural site of the North China Plain: Distribution, source, and risk assessment

The process of frost formation has been studied as an important deposition pathway for removing atmospheric pollutants. However, the removal of organic species during frost formation remains unknown. Gas, PM_2.5 and frost samples were collected in Wangdu, a severely polluted rural site in the North China Plain, during the winter of 2018. The concentrations, distributions, sources, and ecological and health risks of the 16 PAHs in the samples were determined. The 24 h-averaged concentrations of PAHs in the air (gas + PM_2.5) reached 719 ng m^-3, indicating that the local atmosphere was heavily contaminated by PAHs in winter. The average concentrations of PAHs in the frost insoluble reached 27.5 μg g^-1, indicating the strong ambient PAHs deposition during the frost process. The distribution patterns of individual PAH species indicated that the PAHs in the gas influenced the frost samples, and the sources of PAHs in frost samples were highly similar to those in PM_2.5 samples. The calculated lifetime lung cancer risk (LLCR) via inhalation of ambient PAHs was classified as high risks. The average total Benzo(a)pyrene toxic equivalent quotient (TEQ) of PAHs in the frost samples was estimated as 2.50 μg TEQ g^-1, posing a high threat to the ecological environment and health. After the melting of frost, the PAHs are released into the soil. Although the concentrations are diluted, the PAH concentrations could adversely affect the growing vegetation or agricultural activities. The extremely high PAH concentrations and their ecological and health risks require special attention and strict regulation.