Enhanced dewaterability of lake dredged sediments by electrochemical oxidation of peroxydisulfate on BDD anode

Dredged sediments, as a product of mitigating endogenous pollution of rivers and lakes, cause severe environmental pollution without suitable disposal. To reduce dredged sediments, the electrochemical oxidation (EO) of peroxydisulfate (PS) on a boron-doped diamond (BDD) anode (EO/BDD-PS) was utilized to enhance the dewaterability of the dredged sediments. The soluble chemical oxygen demand increased in the EO/BDD-PS system, and more than 70.0% of the specific resistance to filtration was reduced by EO/BDD-PS within 20 min. The optimal conditions were determined to be as follows: current density, 30 mA cm^-2; PS dosage 4 g L^-1; and initial pH, 6.96. After treatment with EO/BDD-PS, the electronegativity of the sludge flocs was alleviated and the particle size increased from 7.61 to 10.64 μm. Furthermore, proteins and polysaccharides were degraded, and tightly bound extracellular polymeric substances (TB-EPS) and loosely bound EPS (LB-EPS) were effectively transported to soluble EPS (S-EPS). Furthermore, humification of organic matter occurred in S-EPS and LB-EPS when the dredged sediment was treated with EO/BDD-PS. Dominant hydroxyl radicals (•OH) and sulfate radicals (SO₄•^-) were generated in the EO/BDD-PS system. Moreover, the efficiency of the filtrate as an electrolyte decreased slightly after recycling five times. Therefore, this method may be economical for enhancing the dewaterability of dredged sediments.