An infrared study of CO₂ activation by holmium ions, Ho⁺ and HoO

We report a combined experimental and computational study of carbon dioxide activation at gas-phase Ho⁺ and HoO⁺ centres. Infrared action spectra of Ho(CO₂)_n⁺ and [HoO(CO₂)_n]⁺ ion-molecule complexes have been recorded in the spectral region 1700-2400 cm^-1 and assigned by comparison with simulated spectra of energetically low-lying structures determined by density functional theory. Little by way of activation is observed in Ho(CO₂)_n⁺ complexes with CO₂ binding end-on to the Ho⁺ ion. By contrast, all [HoO(CO₂)_n]⁺ complexes n ≥ 3 show unambiguous evidence for formation of a carbonate radical anion moiety, . The signature of this structure, a new vibrational band observed around 1840 cm^-1 for n = 3, continues to red-shift monotonically with each successive CO₂ ligand binding with net charge transfer from the ligand rather than the metal centre.