Luminescent Crystalline Carbon- and Nitrogen-Centered Organic Radicals Based on N-Heterocyclic Carbene-Triphenylamine Hybrids

Developing luminescent radicals with tunable emission is a challenging task due to the limitation of alternative skeletons. Herein, a series of carbene-triphenylamine hybrids were prepared by the direct C2-arylation of N-heterocyclic carbenes with 4-bromo-N,N-bis(4-methoxyphenyl)aniline. These hybrids showed multiple redox-active properties and could be converted to carbon-centered luminescent radicals with blue-to-cyan emissions (λ_max : 436-486 nm) or nitrogen-centered luminescent radicals with orange emissions (λ_max : 590-623 nm) through chemical reduction or oxidation, respectively. The radical species were characterized by electron paramagnetic resonance spectroscopy, ultraviolet-visible spectroscopy, and single-crystal X-ray diffractometry analysis. Notably, the corresponding nitrogen-centered radicals exhibited good stability in atmospheric air, and their thermal decomposition temperatures were determined to be above 200 °C. In addition, spectral and theoretical calculations indicate that all radicals exhibit anti-Kasha emissions.