Chitosan grafted tetracarboxylic functionalized magnetic nanoparticles for removal of Pb(II) from an aqueous environment

In this study, the chitosan-grafted tetracarboxylic functionalized magnetic nanoparticle (Fe₃O₄@TCA@CS) was synthesized via in situ co-precipitation process and amidation reaction to improve efficiency of adsorption process and obtain cost-effective adsorbents for removal of toxic Pb(II) metal from aqueous environment. The Fe₃O₄@TCA@CS nanocomposite was analyzed by FTIR, TEM-EDX, TGA, XRD, BET, and Zeta potential. The performance of Fe₃O₄@TCA@CS for Pb(II) ions adsorption was achieved as a function of pH, dose, contact time, initial Pb(II) concentration, and temperature. The influence of coexisting ions such as Na⁺, Ca²⁺, Mg²⁺, and Cd²⁺on removal efficiency of Pb(II) was also investigated. The results revealed that the coexisting ions had little influence on Pb(II) removal efficiency. The pseudo-first-order and Freundlich models were better to describe the adsorption of Pb(II) onto Fe₃O₄@TCA@CS and the maximum adsorption capacity of Pb(II) was 204.92 mg/g at pH:5.5; adsorbent dose: 0.015 g; and temperature: 298 K. Thermodynamic studies revealed that the Pb(II) adsorption onto Fe₃O₄@TCA@CS was an exothermic process. In conclusion, the study provides a new, simple, low-cost, and effective chitosan-based magnetic nanocomposite as a promising adsorbent with excellent adsorption capacity, magnetic separation, and reusability for Pb(II) removal from an aqueous environment.