Retention Secured Nonlinear and Self-Rectifying Analog Charge Trap Memristor for Energy-Efficient Neuromorphic Hardware

A memristive crossbar array (MCA) is an ideal platform for emerging memory and neuromorphic hardware due to its high bitwise density capability. A charge trap memristor (CTM) is an attractive candidate for the memristor cell of the MCA, because the embodied rectifying characteristic frees it from the sneak current issue. Although the potential of the CTM devices has been suggested, their practical viability needs to be further proved. Here, a Pt/Ta₂ O₅ /Nb₂ O_{5- x} /Al₂ O_{3- y} /Ti CTM stack exhibiting high retention and array-level uniformity is proposed, allowing a highly reliable selector-less MCA. It shows high self-rectifying and nonlinear current-voltage characteristics below 1 µA of programming current with a continuous analog switching behavior. Also, its retention is longer than 10⁵ s at 150 °C, suggesting the device is highly stable for non-volatile analog applications. A plausible band diagram model is proposed based on the electronic spectroscopy results and conduction mechanism analysis. The self-rectifying and nonlinear characteristics allow reducing the on-chip training energy consumption by 71% for the MNIST dataset training task with an optimized programming scheme.