Luminescence, Paramagnetic, and Electrochemical Properties of Copper Oxides-Decorated TiO₂/Graphene Oxide Nanocomposites

The properties of newly synthesized Cu₂O/CuO-decorated TiO₂/graphene oxide (GO) nanocomposites (NC) were analyzed aiming to obtain insight into their photocatalytic behavior and their various applications, including water remediation, self-cleaning surfaces, antibacterial materials, and electrochemical sensors. The physico-chemical methods of research were photoluminescence (PL), electron paramagnetic resonance (EPR) spectroscopy, cyclic voltammetry (CV), and differential pulse voltammetry (DPV). The solid samples evidenced an EPR signal that can be attributed to the oxygen-vacancy defects and copper ions in correlation with PL results. Free radicals generated before and after UV-Vis irradiation of powders and aqueous dispersions of Cu₂O/CuO-decorated TiO₂/GO nanocomposites were studied by EPR spectroscopy using two spin traps, DMPO (5,5-dimethyl-1-pyrroline-N-oxide) and CPH (1-hydroxy-3-carboxy-2,2,5,5-tetramethylpyrrolidine), to highlight the formation of hydroxyl and superoxide reactive oxygen species, respectively. The electrochemical characterization of the NC modified carbon-paste electrodes (CPE) was carried out by CV and DPV. As such, modified carbon-paste electrodes were prepared by mixing carbon paste with copper oxides-decorated TiO₂/GO nanocomposites. We have shown that GO reduces the recombination process in TiO₂ by immediate electron transfer from excited TiO₂ to GO sheets. The results suggest that differences in the PL, respectively, EPR data and electrochemical behavior, are due to the different copper oxides and GO content, presenting new perspectives of materials functionalization.