Facilely achieved enhancement of Fenton-like reactions by constructing electric microfields

In this work, we found that the presence of non-active ZnO crystals greatly accelerated the degradation of Bisphenol A (BPA) by 3.7 folds in the peroxymonosulfate (PMS, HSO₅^-)/Co₃O₄ system. Our mechanistic study revealed that the ZnO particles would create negative electric microfields around them, which are closely related with the zeta potentials (ζ) of ZnO and affected by solution pH. According to COMSOL simulation, the electrostatic repulsion between ZnO and PMS would drive HSO₅^- toward active Co₃O₄ surface, leading to the concentration increasing of HSO₅^- around active Co₃O₄ particles, which will then improve the degradation performance. The particle size of ZnO will also affect the promoting effect greatly by COMSOL simulation. Therefore, this study for the first time reveals synergy of electric microfields for enhanced heterogeneous Fenton-like reactions, providing a low-cost and effective strategy for enhanced persulfate catalysis.