Pollution characteristics and ecological risks of trace elements in PM_2.5 over three COALESCE network sites - Bhopal, Mesra, and Mysuru, India

Time-synchronized, 24 h integrated PM_2.5 trace element (TE) measurements made as a part of the COALESCE project (Venkataraman et al., 2020) at Bhopal, Mesra, and Mysore during all of 2019 were analyzed in this study. The concentrations of 15 key elements ranged between 0.05 ng m^-3 and 50 μg m^-3 across the study sites. Pronounced seasonal variation of elements from multiple source classes showed that the crustal origin elements (Al, Si, Fe, Ti, and Ca) peaked during the pre-monsoon season, while the anthropogenic activities driven element (P, S, K, V, Mn, Cu, Zn, and Pb) concentrations increased during the winter and post-monsoon seasons. Spearman correlation coupled with hierarchical clustering separated the matrix of elements into three common clusters at all sites, corresponding to crustal sources, combustion and biomass burning emissions, and industrial/non-exhaust vehicular emissions, respectively. Furthermore, episodes of metal pollution throughout the year were examined using characteristic radar charts of TEs to identify the association between TE sources and poor air quality. For example, maximum metal pollution in Bhopal occurred during the post-monsoon season, attributable to biomass burning, dust storms, industrial and non-exhaust vehicular emissions. Finally, an ecological risk assessment revealed that the risk index was higher than the threshold value of 600 for all heavy metals at all sites. Pb, Cu, and Zn were the top contributors to 'extremely high risk' amongst all heavy metals. Overall, the results show that although TE concentrations at all three locations were much lower than in other urban locations in India, the risk from heavy metals to the ecosystem (and likely to human health) cannot be ignored. The findings warrant a full source apportionment of fine PM to better identify TE-rich source contributions and future studies to examine the atmospheric processing and eco-system uptake of TEs.