Xanchryones I-N, Six Unusual Phloroglucinol-Amino Acid Hybrids from the Leaves of Xanthostemon chrysanthus

Chem Biodivers. 2023 Apr;20(4):e202300234. doi: 10.1002/cbdv.202300234. Epub 2023 Mar 29.

Abstract

Six new phloroglucinol derivatives, xanchryones I-N (1-6), were isolated from the leaves of Xanthostemon chrysanthus. Compounds 1-6 are unusual phloroglucinol-amino acid hybrids constructed through C2 -N and O-C1 ' bonds forming a peculiar oxazole ring. The structures and absolute configurations of compounds 1-6 were determined by MS, NMR, and single-crystal X-ray diffraction. Moreover, the anti-inflammatory and antibacterial activities of these compounds were evaluated.

Keywords: Xanthostemon chrysanthus; phloroglucinol derivatives; phloroglucinol-amino acid hybrids.

MeSH terms

  • Amino Acids / analysis
  • Anti-Bacterial Agents / chemistry
  • Molecular Structure
  • Myrtaceae* / chemistry
  • Phloroglucinol* / chemistry
  • Plant Leaves / chemistry

Substances

  • Phloroglucinol
  • Amino Acids
  • Anti-Bacterial Agents