High-Conductivity Chalcogenide Glasses in Ag-Ga₂Te₃-SnTe Systems and Their Suitability as Thermoelectric Materials

A novel high-conductivity Ag_x[(Ga₂Te₃)₃₄(SnTe)₆₆]_100-x tellurium-based glassy system was fabricated via melt spinning with the glass formation area in the range of x = 0-15 mol %. A bulk Ag₁₀[(Ga₂Te₃)₃₄(SnTe)₆₆]₉₀ glass (A10) was obtained via spark plasma sintering at 450 K using a 5 min dwell time and 400 MPa pressure. The fabricated A10 glass exhibited higher room-temperature conductivity (σ_{300 K} = 46 S m^-1), larger glass transition temperature (T_g = 482 K), and ultralower thermal conductivity (∼0.19 W m^-1 K^-1) compared to those of previously reported Cu-Ge-Te, Cu-As-Te, Cu-Ge-As-Te, and Cu-As-Se-Te glassy systems with the approximate doping concentrations of 5-20%, demonstrating that this distinctive Ag-Ga₂Te₃-SnTe system is interesting materials for thermoelectric applications. The high-conductivity Ag-Ga₂Te₃-SnTe glassy system will extend investigations into similar glassy semiconductors and also can be used for preparing glass ceramics with potential applications in other fields.