Recent advances in core-shell structured catalysts for low-temperature NH₃-SCR of NO_x

Ammonia selective catalytic reduction (NH₃-SCR) of nitrogen oxides is an effective and well-established technology for NO_x removal, but current commercial denitrification catalysts based on V₂O₅-WO₃/TiO₂ have some obvious disadvantages, including narrow operating temperature windows, toxicity, poor hydrothermal stability, and unsatisfied SO₂/H₂O tolerance. To overcome these drawbacks, it is imperative to investigate new types of highly efficient catalysts. In order to design catalysts with outstanding selectivity, activity, and anti-poisoning ability, core-shell structured materials have been widely applied in the NH₃-SCR reaction, which exhibits numerous advantages including the large surface area, the strong synergy interaction of core-shell materials, the confinement effect, and the shielding effect from the shell layer to protect the core. This review summarizes recent developments of core-shell structured catalysts for NH₃-SCR, including basic classification, synthesis methods, and a detailed description of the performance and mechanisms of each type of catalyst. It is hoped that the review will stimulate future developments in NH₃-SCR technology, leading to novel catalyst designs with improved denitrification performance.