Magnetic graphene oxide carbon dot nanocomposites as an efficient quantification tool against parabens in water and cosmetic samples

A new method is developed for the simultaneous detection and extraction of parabens, including methyl paraben (MP), ethyl paraben (EP), propyl paraben (PP), and butyl paraben (BP), based on magnetic graphene oxide carbon dot nanocomposites (Fe₃O₄@GO@CD). Fe₃O₄@GO@CD has been synthesized using one pot hydrothermal method by intercalating iron oxide and carbon dots between the layers of graphene oxide. Fe₃O₄@GO@CD was applied as the magnetic solid phase sorbent for the simultaneous extraction and detection of parabens from water (tap and river water) and cosmetic samples (hair serum and sunscreen cream). MP was measured at concentration of 0.25-0.26 ng/mL in hair serum, while PP at 0.32-0.33 ng/mL in sunscreen cream. Notably, good recoveries (88.74-98.03%; RSD = 2.31-6.88%) for river and tap water with detection limit of 0.039-0.046 ng/mL were attained. The method has good cyclability up to 16 cycles and was highly repeatable. All these findings suggest that the Fe₃O₄@GO@CD would be potential sorbent for the analysis of parabens.