Characterization of a recombinant factor IX molecule fused to coagulation factor XIII-B subunit

Haemophilia. 2023 Nov;29(6):1483-1489. doi: 10.1111/hae.14855. Epub 2023 Sep 14.

Abstract

Introduction and aim: Severe haemophilia B (HB) is characterized by spontaneous bleeding episodes, mostly into joints. Recurrent bleeds lead to progressive joint destruction called haemophilic arthropathy. The current concept of prophylaxis aims at maintaining the FIX level >3-5 IU/dL, which is effective at reducing the incidence of haemophilic arthropathy. Extended half-life FIX molecules make it easier to achieve these target trough levels compared to standard FIX concentrates. We previously reported that the fusion of a recombinant FIX (rFIX) to factor XIII-B (FXIIIB) subunit prolonged the half-life of the rFIX-LXa-FXIIIB fusion molecule in mice and rats 3.9- and 2.2-fold, respectively, compared with rFIX-WT. However, the mechanism behind the extended half-life was not known.

Materials and methods: Mass spectrometry and ITC were used to study interactions of rFIX-LXa-FXIIIB with albumin. Pharmacokinetic analyses in fibrinogen-KO and FcRn-KO mice were performed to evaluate the effect of albumin and fibrinogen on in-vivo half-life of rFIX-LXa-FXIIIB. Finally saphenous vein bleeding model was used to assess in-vivo haemostatic activity of rFIX-LXa-FXIIIB.

Results and conclusion: We report here the key interactions that rFIX-LXa-FXIIIB may have in plasma are with fibrinogen and albumin which may mediate its prolonged half-life. In addition, using the saphenous vein bleeding model, we demonstrate that rFIX-FXIIIB elicits functional clot formation that is indistinguishable from that of rFIX-WT.

Keywords: albumin; extended half-life Factor IX; factor XIII-B sub-unit; fibrinogen; fusion protein.

MeSH terms

  • Albumins
  • Animals
  • Factor IX / genetics
  • Factor IX / pharmacology
  • Factor IX / therapeutic use
  • Factor XIII / pharmacology
  • Factor XIII / therapeutic use
  • Fibrinogen / therapeutic use
  • Half-Life
  • Hemophilia B* / drug therapy
  • Hemorrhage / prevention & control
  • Hemostatics* / therapeutic use
  • Joint Diseases* / drug therapy
  • Mice
  • Rats
  • Recombinant Fusion Proteins / pharmacokinetics
  • Recombinant Fusion Proteins / therapeutic use
  • Recombinant Proteins / chemistry
  • Recombinant Proteins / pharmacology
  • Recombinant Proteins / therapeutic use
  • Vascular Diseases*

Substances

  • Factor IX
  • Factor XIII
  • Recombinant Fusion Proteins
  • Hemostatics
  • Albumins
  • Fibrinogen
  • Recombinant Proteins