Reduction-induced hapticity increase in a silacycle-bridged biaryl-based ligand coordinated to an iron center

Yuto Suga; Yusuke Sunada

doi:10.1039/d3dt03788f

Reduction-induced hapticity increase in a silacycle-bridged biaryl-based ligand coordinated to an iron center

Dalton Trans. 2024 Jan 16;53(3):862-865. doi: 10.1039/d3dt03788f.

Authors

Yuto Suga¹, Yusuke Sunada^{1

2}

Affiliations

¹ Department of Applied Chemistry, School of Engineering, The University of Tokyo, 4-6-1, Komaba, Meguro-ku, Tokyo 153-8505, Japan.
² Institute of Industrial Science, The University of Tokyo, 4-6-1, Komaba, Meguro-ku, Tokyo 153-8505, Japan.

PMID: 37987085
DOI: 10.1039/d3dt03788f

Abstract

An Fe(II) bromide complex supported by a bidentate phosphine ligand and an η¹(C)-coordinated six-membered silacycle-bridged biphenyl-based ligand is converted upon reduction into an Fe(I) complex in which the hapticity of the silacycle-based ligand increases from η¹ to η⁵.