Pt-Clusters-Equipped Antioxidase-Like Biocatalysts as Efficient ROS Scavengers for Treating Periodontitis

Small. 2024 Apr;20(17):e2306966. doi: 10.1002/smll.202306966. Epub 2023 Dec 7.

Abstract

Developing high-efficiency artificial biocatalysts for scavenging reactive oxygen species (ROS) is critical for treating inflammation diseases and promoting tissue regeneration. By mimicking the active sites in catalase, here, a Pt-clusters-equipped antioxidase-like biocatalysts (Pt─CN) with superior catalytic abilities for stem cell protection and periodontitis treatment are reported. Owing to the excellent effects of multiple Pt clusters, Pt─CN yields exceptional catalytic ROS-scavenging activities for multiple types of ROS. In vitro studies show that Pt─CN can effectively protect stem cell survival, adhesion, and differentiation in a high ROS levels microenvironment. Additionally, Pt─CN can reduce the M1/M2 ratio of macrophages when stimulated by lipopolysaccharide. In vivo treatment of mouse periodontitis further confirms the protection against bone loss and reduction in the inflammatory response. This study provides a basis for the application of biocatalysts with Pt catalytic center in macrophage polarization, stem cell protection, and periodontitis treatment, thus offering a new strategy for the design of high-performance artificial biocatalysts.

Keywords: artificial biocatalysts; macrophage repolarization; periodontitis; reactive oxygen species; stem cell protection.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Antioxidants / chemistry
  • Antioxidants / metabolism
  • Antioxidants / pharmacology
  • Biocatalysis
  • Catalysis
  • Cell Differentiation / drug effects
  • Free Radical Scavengers / chemistry
  • Free Radical Scavengers / pharmacology
  • Macrophages / drug effects
  • Macrophages / metabolism
  • Mice
  • Periodontitis* / drug therapy
  • Periodontitis* / metabolism
  • Platinum / chemistry
  • Platinum / pharmacology
  • Reactive Oxygen Species* / metabolism
  • Stem Cells / cytology
  • Stem Cells / metabolism

Substances

  • Reactive Oxygen Species
  • Platinum
  • Antioxidants
  • Free Radical Scavengers