Fluorescence color change of supramolecular polymer networks controlled by crown ether-cation recognition

Chemistry. 2024 Feb 26;30(12):e202303569. doi: 10.1002/chem.202303569. Epub 2024 Jan 10.

Abstract

We report a fluorescent supramolecular polymer networks (SPNs) system based on crown ether-cation recognition. The polymer side chains bear ammonium cations, which can be recognized by host molecules with a B15C5 unit and a quinoline group at each end. The quinoline group makes the host molecule exhibit blue fluorescence. After the formation of SPNs, the recognition of the crown ether-cation transforms the blue fluorescence into yellow fluorescence. The accompanying fluorescence color change during the formation of SPNs makes it with potential applications in the fields of display, printing, information storage, and bioimaging.

Keywords: Fluorescence; Host-guest systems; Molecular recognition; Polymers; Supramolecular chemistry.