Adsorption of Diclofenac and PFBS on a Hair Keratin Dimer

J Phys Chem B. 2024 Jan 11;128(1):45-55. doi: 10.1021/acs.jpcb.3c04997. Epub 2023 Dec 28.

Abstract

Environmental pollution by man-made toxic and persistent organic compounds, found throughout the world in surface and groundwater, has various negative effects on aquatic life systems and even humans. Therefore, it is important to develop and improve water treatment technologies capable of removing such substances from wastewater and purifying drinking water. The two substances investigated are the widely used painkiller diclofenac and a member of the class of "forever chemicals", perfluorobutanesulfonate. Both are known to have serious negative effects on living organisms, especially under long-term exposure, and are detectable in human hair, suggesting adsorption to a part of the hair fiber complex. In this study, a human hair keratin dimer is investigated for its ability to absorb diclofenac and perfluorobutanesulfonate. Initial predictions for binding sites are obtained via molecular docking and subjected to molecular dynamics simulations for more than 1 μs. The binding affinities obtained by the linear interaction energy method are high enough to motivate further research on human hair keratins as a sustainable, low-cost, and easily allocatable filtration material.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adsorption
  • Diclofenac*
  • Fluorocarbons*
  • Hair / chemistry
  • Humans
  • Keratins, Hair-Specific* / analysis
  • Molecular Docking Simulation
  • Sulfonic Acids*

Substances

  • perfluorobutanesulfonic acid
  • Diclofenac
  • Keratins, Hair-Specific
  • Fluorocarbons
  • Sulfonic Acids