Construction of a stable radical hydrogen-bonded metal-organic framework with functionalized tetrathiafulvalene linkers

Jian Su; Xiao Han; Si-Wen Ke; Xiao-Cheng Zhou; Shuai Yuan; Mengning Ding; Jing-Lin Zuo

doi:10.1039/d4cc01152j

Construction of a stable radical hydrogen-bonded metal-organic framework with functionalized tetrathiafulvalene linkers

Chem Commun (Camb). 2024 May 30;60(45):5812-5815. doi: 10.1039/d4cc01152j.

Authors

Jian Su^{1

2}, Xiao Han¹, Si-Wen Ke¹, Xiao-Cheng Zhou¹, Shuai Yuan¹, Mengning Ding¹, Jing-Lin Zuo¹

Affiliations

¹ State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, P. R. China.
² School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing, 210094, P. R. China. [email protected].

PMID: 38747473
DOI: 10.1039/d4cc01152j

Abstract

A stable two-dimensional radical hydrogen-bonded metal-organic framework, constructed using a modified tetrathiafulvalene-tetrabenzoate ((2-Me)-H₄TTFTB) linker and Cd²⁺ ions, exhibits a high electrical conductivity of 4.1 × 10^-4 S m^-1 and excellent photothermal conversion with a temperature increase of 137 °C in 15 s under the irradiation of a 0.7 W cm^-2 808 nm laser.