Crafting Docetaxel-Loaded Albumin Nanoparticles Through a Novel Thermal-Driven Self-Assembly/Microfluidic Combination Technology: Formulation, Process Optimization, Stability, and Bioavailability

Int J Nanomedicine. 2024 Jun 1:19:5071-5094. doi: 10.2147/IJN.S457482. eCollection 2024.

Abstract

Background: The commercial docetaxel (DTX) formulation causes severe side effects due to polysorbate 80 and ethanol. Novel surfactant-free nanoparticle (NP) systems are needed to improve bioavailability and reduce side effects. However, controlling the particle size and stability of NPs and improving the batch-to-batch variation are the major challenges.

Methods: DTX-loaded bovine serum albumin nanoparticles (DTX-BSA-NPs) were prepared by a novel thermal-driven self-assembly/microfluidic technology. Single-factor analysis and orthogonal test were conducted to obtain the optimal formulation of DTX-BSA-NPs in terms of particle size, encapsulation efficiency (EE), and drug loading (DL). The effects of oil/water flow rate and pump pressure on the particle size, EE, and DL were investigated to optimize the preparation process of DTX-BSA-NPs. The drug release, physicochemical properties, stability, and pharmacokinetics of NPs were evaluated.

Results: The optimized DTX-BSA-NPs were uniform, with a particle size of 118.30 nm, EE of 89.04%, and DL of 8.27%. They showed a sustained release of 70% over 96 hours and an increased stability. There were some interactions between the drug and excipients in DTX-BSA-NPs. The half-life, mean residence time, and area under the curve (AUC) of DTX-BSA-NPs increased, but plasma clearance decreased when compared with DTX.

Conclusion: The thermal-driven self-assembly/microfluidic combination method effectively produces BSA-based NPs that improve the bioavailability and stability of DTX, offering a promising alternative to traditional formulations.

Keywords: DTX-BSA nanoparticles; in-vitro release; microfluidic technology; pharmacokinetics; thermal-driven self-assembly.

MeSH terms

  • Animals
  • Antineoplastic Agents / administration & dosage
  • Antineoplastic Agents / chemistry
  • Antineoplastic Agents / pharmacokinetics
  • Biological Availability*
  • Docetaxel* / administration & dosage
  • Docetaxel* / chemistry
  • Docetaxel* / pharmacokinetics
  • Drug Carriers / chemistry
  • Drug Carriers / pharmacokinetics
  • Drug Compounding / methods
  • Drug Liberation
  • Drug Stability*
  • Male
  • Nanoparticles* / chemistry
  • Particle Size*
  • Rats
  • Rats, Sprague-Dawley
  • Serum Albumin, Bovine* / administration & dosage
  • Serum Albumin, Bovine* / chemistry
  • Serum Albumin, Bovine* / pharmacokinetics
  • Taxoids / administration & dosage
  • Taxoids / chemistry
  • Taxoids / pharmacokinetics

Substances

  • Docetaxel
  • Serum Albumin, Bovine
  • Taxoids
  • Antineoplastic Agents
  • Drug Carriers