Development and characterization of polyethylene oxide and guar gum-based hydrogel; a detailed in-vitro analysis of degradation and drug release kinetics

Int J Biol Macromol. 2024 Jul;273(Pt 1):132824. doi: 10.1016/j.ijbiomac.2024.132824. Epub 2024 Jun 8.

Abstract

Herein, we synthesized hydrogel films from crosslinked polyethylene oxide (PEO) and guar gum (GG) which can offer hydrophilicity, antibacterial efficacy, and neovascularization. This study focuses on synthesis and material/biological characterization of rosemary (RM) and citric acid (CA) loaded PEO/GG hydrogel films. Scanning Electron Microscopy images confirmed the porous structure of the developed hydrogel film matrix (PEO/GG) and the dispersion of RM and CA within it. This porous structure promotes moisture adsorption, cell attachment, proliferation, and tissue layer formation. Fourier Transform Infrared Spectroscopy (FTIR) further validated the crosslinking of the PEO/GG matrix, as confirmed by the appearance of C-O-C linkage in the FTIR spectrum. PEO/GG and PEO/GG/RM/CA revealed similar degradation and release kinetics in Dulbecco's Modified Eagle Medium, Simulated Body Fluid, and Phosphate Buffer Saline (degradation of ∼55 % and release of ∼60 % RM in 168 h.). The developed hydrogel film exhibited a zone of inhibition against Escherichia. coli (2 mm) and Staphylococcus. aureus (9 mm), which can be attributed to the presence of RM in the hydrogel film. Furthermore, incorporating CA in the hydrogel film promoted neovascularization, as confirmed by the Chorioallantoic Membrane Assay. The developed RM and CA-loaded PEO/GG-based hydrogel films offered suitable in-vitro properties that may aid in potential wound healing applications.

Keywords: Antibacterial; Degradation; Hydrogel film; Release kinetics; Sustained.

MeSH terms

  • Animals
  • Anti-Bacterial Agents* / chemistry
  • Anti-Bacterial Agents* / pharmacology
  • Chorioallantoic Membrane / drug effects
  • Drug Carriers / chemistry
  • Drug Liberation*
  • Escherichia coli / drug effects
  • Galactans* / chemistry
  • Hydrogels* / chemistry
  • Kinetics
  • Mannans* / chemistry
  • Plant Gums* / chemistry
  • Polyethylene Glycols* / chemistry
  • Staphylococcus aureus / drug effects

Substances

  • Mannans
  • Galactans
  • Plant Gums
  • guar gum
  • Polyethylene Glycols
  • Hydrogels
  • Anti-Bacterial Agents
  • Drug Carriers