Design, in silico Evaluation, and Determination of Antitumor Activity of Potential Inhibitors Against Protein Kinases: Application to BCR-ABL Tyrosine Kinase

Biochemistry (Mosc). 2024 Jun;89(6):1094-1108. doi: 10.1134/S0006297924060099.

Abstract

Despite significant progress made over the past two decades in the treatment of chronic myeloid leukemia (CML), there is still an unmet need for effective and safe agents to treat patients with resistance and intolerance to the drugs used in clinic. In this work, we designed 2-arylaminopyrimidine amides of isoxazole-3-carboxylic acid, assessed in silico their inhibitory potential against Bcr-Abl tyrosine kinase, and determined their antitumor activity in K562 (CML), HL-60 (acute promyelocytic leukemia), and HeLa (cervical cancer) cells. Based on the analysis of computational and experimental data, three compounds with the antitumor activity against K562 and HL-60 cells were identified. The lead compound efficiently suppressed the growth of these cells, as evidenced by the low IC50 values of 2.8 ± 0.8 μM (K562) and 3.5 ± 0.2 μM (HL-60). The obtained compounds represent promising basic structures for the design of novel, effective, and safe anticancer drugs able to inhibit the catalytic activity of Bcr-Abl kinase by blocking the ATP-binding site of the enzyme.

Keywords: Bcr-Abl inhibitors; Bcr-Abl tyrosine kinase; antitumor activity; biomedical testing; computer-aided drug design; molecular docking; molecular dynamics.

MeSH terms

  • Antineoplastic Agents* / chemistry
  • Antineoplastic Agents* / pharmacology
  • Antineoplastic Agents* / therapeutic use
  • Cell Proliferation / drug effects
  • Computer Simulation
  • Drug Design*
  • Drug Screening Assays, Antitumor
  • Fusion Proteins, bcr-abl* / antagonists & inhibitors
  • Fusion Proteins, bcr-abl* / metabolism
  • HL-60 Cells
  • HeLa Cells
  • Humans
  • K562 Cells
  • Molecular Docking Simulation
  • Protein Kinase Inhibitors* / chemistry
  • Protein Kinase Inhibitors* / pharmacology
  • Protein Kinase Inhibitors* / therapeutic use
  • Pyrimidines / chemistry
  • Pyrimidines / pharmacology

Substances

  • Protein Kinase Inhibitors
  • Antineoplastic Agents
  • Fusion Proteins, bcr-abl
  • Pyrimidines