Superionic conduction in a Mg2+-containing covalent organic framework at intermediate temperature

Akinori Mohri; Yuki Oami; Masaaki Sadakiyo

doi:10.1039/d4dt01424c

Superionic conduction in a Mg²⁺-containing covalent organic framework at intermediate temperature

Dalton Trans. 2024 Aug 13;53(32):13326-13329. doi: 10.1039/d4dt01424c.

Authors

Akinori Mohri¹, Yuki Oami¹, Masaaki Sadakiyo¹

Affiliation

¹ Department of Applied Chemistry, Faculty of Science Division I, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan. [email protected].

PMID: 39101225
DOI: 10.1039/d4dt01424c

Abstract

We report superionic conduction in a Mg²⁺-containing covalent organic framework (COF) at intermediate temperature in the absence of guest vapors. A COF containing Mg²⁺ carriers and polyethylene oxide (PEO) chains in its channels (TPB-PEO-9-COF-Mg) was synthesized. TPB-PEO-9-COF-Mg showed superionic conductivity above 10^-4 S cm^-1 under dry N₂ at 160 °C.