Puerarin-Loaded Liposomes Co-Modified by Ischemic Myocardium-Targeting Peptide and Triphenylphosphonium Cations Ameliorate Myocardial Ischemia-Reperfusion Injury

Int J Nanomedicine. 2024 Aug 7:19:7997-8014. doi: 10.2147/IJN.S468394. eCollection 2024.

Abstract

Purpose: Mitochondrial damage may lead to uncontrolled oxidative stress and massive apoptosis, and thus plays a pivotal role in the pathological processes of myocardial ischemia-reperfusion (I/R) injury. However, it is difficult for the drugs such as puerarin (PUE) to reach the mitochondrial lesion due to lack of targeting ability, which seriously affects the expected efficacy of drug therapy for myocardial I/R injury.

Methods: We prepared triphenylphosphonium (TPP) cations and ischemic myocardium-targeting peptide (IMTP) co-modified puerarin-loaded liposomes (PUE@T/I-L), which effectively deliver the drug to mitochondria and improve the effectiveness of PUE in reducing myocardial I/R injury.

Results: In vitro test results showed that PUE@T/I-L had sustained release and excellent hemocompatibility. Fluorescence test results showed that TPP cations and IMTP double-modified liposomes (T/I-L) enhanced the intracellular uptake, escaped lysosomal capture and promoted drug targeting into the mitochondria. Notably, PUE@T/I-L inhibited the opening of the mitochondrial permeability transition pore, reduced intracellular reactive oxygen species (ROS) levels and increased superoxide dismutase (SOD) levels, thereby decreasing the percentage of Hoechst-positive cells and improving the survival of hypoxia-reoxygenated (H/R)-injured H9c2 cells. In a mouse myocardial I/R injury model, PUE@T/I-L showed a significant myocardial protective effect against myocardial I/R injury by protecting mitochondrial integrity, reducing myocardial apoptosis and decreasing infarct size.

Conclusion: This drug delivery system exhibited excellent mitochondrial targeting and reduction of myocardial apoptosis, which endowed it with good potential extension value in the precise treatment of myocardial I/R injury.

Keywords: ischemic myocardium-targeting peptide; liposomes; mitochondrial targeting; puerarin; triphenylphosphonium cations.

MeSH terms

  • Animals
  • Apoptosis / drug effects
  • Cations / chemistry
  • Drug Delivery Systems / methods
  • Isoflavones* / administration & dosage
  • Isoflavones* / chemistry
  • Isoflavones* / pharmacokinetics
  • Isoflavones* / pharmacology
  • Liposomes* / chemistry
  • Male
  • Mice
  • Myocardial Reperfusion Injury* / drug therapy
  • Myocardium / metabolism
  • Myocardium / pathology
  • Organophosphorus Compounds* / administration & dosage
  • Organophosphorus Compounds* / chemistry
  • Organophosphorus Compounds* / pharmacokinetics
  • Organophosphorus Compounds* / pharmacology
  • Oxidative Stress / drug effects
  • Peptides / administration & dosage
  • Peptides / chemistry
  • Peptides / pharmacology
  • Reactive Oxygen Species / metabolism

Substances

  • Liposomes
  • puerarin
  • Isoflavones
  • Organophosphorus Compounds
  • Reactive Oxygen Species
  • Cations
  • Peptides
  • triphenylphosphonium