Ligand effects on gas adsorption in nanoporous phthalocyanine crystals

Nikolaos-Angelos Stamos; Charles J McMonagle; Gemma F Turner; David R Allan; Mark R Warren; Anna J Warren; Neil B McKeown; Stephen A Moggach

doi:10.1039/d4cc03896g

Ligand effects on gas adsorption in nanoporous phthalocyanine crystals

Chem Commun (Camb). 2024 Oct 8;60(81):11508-11511. doi: 10.1039/d4cc03896g.

Authors

Nikolaos-Angelos Stamos¹, Charles J McMonagle², Gemma F Turner³, David R Allan⁴, Mark R Warren⁴, Anna J Warren⁴, Neil B McKeown¹, Stephen A Moggach³

Affiliations

¹ EastChem School of Chemistry, David Brewster Road, The University of Edinburgh, Edinburgh, EH9 3FJ, UK.
² Swiss-Norwegian Beamlines, European Synchrotron Radiation Facility, Grenoble 38043, France.
³ School of Molecular Sciences, The University of Western Australia, 35 Stirling Highway, Crawley, Perth, WA 6009, Australia. [email protected].
⁴ Diamond House, Harwell Science and Innovation Campus, Fermi Ave, Didcot OX11 0DE, UK.

PMID: 39314127
DOI: 10.1039/d4cc03896g

Abstract

X-ray diffraction is used to study the sorption of CO and NO in two phthalocyanine nanoporous crystals (PNCs) with 4,4' bipyridine or 4,4' bipyrimidine trans coordinated to open Co²⁺ sites, demonstrating how the trans coordinated ligands influence the gas sorption properties and structures of the PNCs.