Thermomechanical Assessment of Recovered PA12 Powders with Basalt Filler for Automotive Components

Polymers (Basel). 2024 Sep 24;16(19):2682. doi: 10.3390/polym16192682.

Abstract

Additive manufacturing processes allow for precise and efficient production, but it is estimated that one-third of the materials used results in waste. Further improvement in a sustainable perspective could come from the ability to manage these scraps and from the exploration of different routes for recovery and reuse. The Selective Laser Sintering process is particularly sensitive to this issue due to the waste ratio which can reach a very high quantity of not-sintered virgin powders. In this research study, recovered PA12 powders, preliminarily characterized through thermal and mechanical analysis, were mixed with 15% basalt powder to improve their aspect and thermomechanical resistance. The influence of basalt powder (BP) on mechanical properties as well as on the thermal stability of polyamide12 (PA12) powder composites was investigated. A study conducted on mechanical properties showed that polymeric composites' stiffness and hardness were influenced by adding filler, thus improving mechanical parameters. On the other hand, the application of thermogravimetric analysis allowed us to determine the composite's thermal stability. The objective is to obtain a recovered fully biobased material that could be used to substitute the petroleum-derived polymeric ones currently employed in the production of interiors and shells in the automotive sector.

Keywords: DMTA; PA12; basalt; biobased; thermomechanical analysis.

Grants and funding

The authors gratefully acknowledge the funding provided by Ministry of University and Research, grant number 2022FBB37P, Project Title “RELIVE—REcycling of pLastic wastes integrating extrusion and additive manufacturing techniques”.