In this study, the reaction between phosphazene superbases and a chlorophosphazene trimer ([PCl2N]3) has been investigated. In this room temperature reaction, the phosphazene superbase (Me2N)3PN(Me2N)2P═NEt, commonly known as P2Et, was shown to behave as a nucleophile, displacing one of the chlorides from [PCl2N]3 and producing the tadpole-like structure 1. The reaction described herein is one of the few instances of a phosphazene superbase behaving as a nucleophile rather than a Brønsted base. Once formed, this structure contains contrasting reactivity, containing a weakly basic phosphazene head while maintaining a highly basic phosphazene tail of the tadpole. The mechanism of the reaction was explored by investigating the potential energy surface through density functional theory calculations at the B3LYP/6-311+G(d,p) level of quantum mechanical theory. It was determined that the reaction of P2Et with [PCl2N]3 followed a stepwise process beginning with the substitution of P2Et onto [PCl2N]3 with the concurrent loss of chloride. Subsequently, the chloride attacks the ethyl group of the P2Et moiety, and ethyl chloride is released, producing 1. Compound 1 was further characterized via 31P NMR spectroscopy, mass spectrometry, and X-ray crystallography.