Radionuclides' Dispersion from Coal-Fired Brick Kilns: Geo-Environmental Processes, Potential Risks and Management

Arch Environ Contam Toxicol. 2024 Oct 29. doi: 10.1007/s00244-024-01096-4. Online ahead of print.

Abstract

In order to investigate the distributions and possible dispersion mechanism(s) of naturally occurring radioactive materials (NORMs: 226Ra, 232Th, and 40K) from coal-based brick kilns, a systematic set (n = 60) of coal, ash, surface-soil, and subsurface soil samples were analyzed. High-quality analytical data of U, Th and K obtained from HPGe detector and TRIGA Mark-II research reactor-based neutron activation analysis were converted to the corresponding radioactivities. Average (n = 10) radioactivities of 226Ra, 232Th, and 40 K in coal samples were 15.6, 16.7, and 145.5 Bq.kg-1, respectively, where only 40 K surpassed the corresponding global mean value. Average (n = 10) radioactivities of 226Ra, 232Th, and 40 K in ash samples were 62.7, 88.5, and 521 Bq.kg-1, respectively, where only 226Ra was within the established limit. In soil samples, average (n = 40) activities of 226Ra, 232Th, and 40 K were 62.7, 95.1, and 641 Bq.kg-1, respectively, which have surpassed the corresponding worldwide mean values. The observed differences in activity levels between soil samples collected near and far from the kilns, as well as between topsoil and subsoil samples, suggest the presence of distinct transport mechanisms for NORMs within the pedosphere. Dispersions of NORMs from the brick kilns to the ambient pedosphere are largely governed by aerodynamic convection and hydrodynamic leaching. These mechanisms are also influenced by geochemical mobility and relative solubility of NORMs, as well as factors such as rainfall patterns and wind-flow direction. Radiological indices invoke long-term carcinogenic-risks, whereas aerodynamic convection of finer particles (coal fly ash) from chimneys can cause significant health hazards to the nearby dwellers. Scientific processes as well as public awareness are essential to mitigate the risks.