Hydrophobic bio-based foam prepared from recycled pulp fiber and its properties

Int J Biol Macromol. 2024 Oct 28;282(Pt 3):136989. doi: 10.1016/j.ijbiomac.2024.136989. Online ahead of print.

Abstract

Compared with traditional petroleum-based foam materials, cellulosic foam materials have significant advantages in terms of economy and environmental protection. However, the traditional cellulose-based foams have some problems such as high energy consumption in the preparation process. In this study, the recycled pulp foam (RPF) with ultra-light density (12.69 kg/m3 ~ 13.83 kg/m3) and high porosity (99.07 % ~ 99.15 %) was prepared by mechanical stirring using waste corrugated cardboard as the main raw material and further hydrophobically modified using rosin. The prepared r-RPF foam has excellent hydrophobicity with the water contact angle remaining 132.9° after 20 s. In addition, the rosin coating enhances the mechanical properties of r-RPF, and the stress of r-RPF at 50 % strain is increased by 97 %. It should be noted that after rosin treatment, the compressive strength and elasticity of r-RPF were improved. The r-RPF was stable in water and had a high oil adsorption capacity (7.8 to 28.13 g/g), which had the potential to treat current oily wastewater.

Keywords: Bio-based; Foam; Hydrophobic; Recycled pulp.