Natural Pitch-Derived Carbon Networks Induced Lattice Strain Engineering in Nickel-Based Heterostructures Enables Efficient Anodes for Sodium-Ion Batteries

The development of high-performance sodium-ion batteries (SIBs) relies on enhancing the electrochemical properties of the electrodes, particularly the transition metal compounds (TMCs) through effective carbon coatings. Herein, a straightforward approach using polymerized natural pitch-derived carbon (PNPC) via step-growth polymerization regulates the lattice strain in Ni₃S₂-NiO heterostructures (NSNO) on nickel foam (NF). This method replaces the complex multistep carbon coatings with a cost-effective liquid-phase application of PNPC, followed by pyrolysis to create PNPC@NSNO/NF. Comparative analysis shows that PNPC effectively modulates lattice strain, achieving 3.50% tensile strain compared to 5.60% for non-polymerized carbon. The optimized PNPC@NSNO/NF electrode exhibits exceptional high areal capacity of 2.72 mAh cm^-2@1 mA cm^-2, impressive rate capability, and 97.28% capacity retention after 200 cycles. The enhanced contact area and electrical conductivity provided by the PNPC improve charge transfer kinetics and overall performance. Theoretical analyses confirm that the PNPC@NSNO/NF electrode with 3.50% lattice strain lowers the Na⁺ diffusion barrier, enhances charge transfer, and improves charge distribution, boosting the electrode performance. This work establishes a straightforward method for synthesizing lattice-strained SIB anodes, highlighting its potential for advancing SIB technology.