In this work, benefitting from the sensitive pH-responsiveness of both meso-tetra-(4-sulfonatophenyl) porphyrin (TPPS4) and calixpyridinium, and their controllable strong noncovalent interactions, the first orthogonal dual-functional visual sensor for simultaneously and separately detecting acidic and alkaline substances without interference by using UV-Vis absorption and fluorescence emission spectra with both "turn on" signal changes was constructed by the supramolecular assembly of calixpyridinium with TPPS4. Color and fluorescence orthogonal dual-functional visual "turn-on" sensing for acidic and alkaline glyphosate and additive by calixpyridinium-TPPS4 sensor was further practically applied. The preparation of this sensor is quite simple in an environmentally friendly water medium. Only 2 μM calixpyridinium and 3 μM TPPS4 are needed to construct this assembly sensor. This sensor has a good biocompatibility, a high selectivity and sensitivity. Moreover, calixpyridinium-TPPS4 sensor can also be applied as a thermal switch and a light controlled anti-counterfeit material.
Keywords: Assembly; Calixpyridinium; Host−guest systems; Macrocycles; Supramolecular chemistry.
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