Metalloporphyrinic metal-organic frameworks for enhanced photocatalytic degradation of a mustard gas simulant

Chem Commun (Camb). 2024 Dec 17;61(1):77-80. doi: 10.1039/d4cc03890h.

Abstract

Four metalloporphyrinic metal-organic frameworks (MOFs) were successfully synthesized and exhibited enhanced activities for the photooxidation of a sulfur mustard simulant, 2-chloroethyl ethyl sulfide (CEES). Among them, a Sn-porphyrin functionalized 2D MOF, namely CSLA-21-NH2(Sn), showed a half-life of 1.5 min for CEES oxidation under blue LED, featuring as one of the fastest photocatalysts for CEES degradation.