Influence of the mass percentage of binders on the properties of LHC

Sci Rep. 2024 Nov 7;14(1):27143. doi: 10.1038/s41598-024-78638-2.

Abstract

This paper investigates the effects on the physical and mechanical properties and microstructure of lime-hemp concrete (LHC) materials at different binder mass ratios. A mixture of three cementitious materials, slaked lime, cement, and coal gangue powder, was used as binder, and hemp shives were used as concrete aggregate, and five test groups were designed, i.e., binder/hemp shives (B/H) mass ratios of 1.2, 1.4, 1.6, 1.8, and 2.0. The physical properties of LHC, including density, drying rate, water absorption, thermal conductivity coefficients, and mechanical properties (compressive strength and flexural strength) with different binder ratios were investigated. In addition, the microstructural properties of 56d LHC were investigated by SEM, XRD, and TG-DTG micro-scale analysis methods. The results showed that with the increase in binder content, the drying speed of LHC became faster, the thermal conductivity coefficients, compressive strength, and flexural strength increased, and the water absorption was just the opposite. With a fit ratio of 2.0, the strength is the greatest and the toughness is the best; with a fit ratio of 1.2, the thermal conductivity coefficient is the smallest and the insulation effect is the best. In addition, the hydration of the binder produced different forms of hydration products (CaCO3 and C-S-H), and the hydration products increased in quantity with the increase of the binder, resulting in stronger CaCO3 and C-S-H diffraction peaks. The hydration products produce a better bond with the rough cannabis particle surface, filling the internal voids of the LHC, improving the density of the material, and enhancing the mechanical properties of the material.

Keywords: Drying rate; Mechanical properties; Thermal conductivity coefficients; Water absorption.