Agent-free, highly sensitive, and simply operated Ag+ sensor with molybdenum disulfide-based field effect transistor

Talanta. 2024 Oct 31:283:127141. doi: 10.1016/j.talanta.2024.127141. Online ahead of print.

Abstract

Ag+, as a good bactericidal reagent, has been extensively used to prevent the growth and spread of bacteria and viruses. However, overcommit of Ag+ would leave residues in environments, which is toxic to the human body even under minimal exposure. In this case, a fast and high selective sensing method based on field effect transistors (FET) has been proposed for monitoring Ag+ in aqueous solutions. Through coordination interaction, Ag + could be spontaneously adsorbed on the surface of the sensing material MoS2 and affect its electronic carrier transport behavior. The MoS2-based FET sensor show outstanding sensing performance to Ag+ including short response time (60 s), good linear relationship (R2 = 0.97), low detection limit (10-10 mol/L) and high selectivity, which could meet the permissible criterion of Ag+ in drinking water by the World Health Organization (0.93 × 10-6 mol/L). This study will promote the application of FET sensors in environmental analysis, and provide important guidance to realize rapid, on-site or in-situ monitoring of heavy metals in aqueous solutions.

Keywords: Aqueous solutions; Field effect transistors; Molybdenum disulfide; Sensor; Silver ion.