Dual Photoswitching of a Diarylethene Ligand-Anchored Hofmann-Type Spin-Crossover Compound

Yu-Meng Zhao; Jie-Sheng Hu; Xue-Yang Ji; Zhi-Kun Liu; Ling-Tai Yue; Meng Yu; Jun Tao

doi:10.1021/acs.inorgchem.4c04268

Dual Photoswitching of a Diarylethene Ligand-Anchored Hofmann-Type Spin-Crossover Compound

Inorg Chem. 2024 Nov 11. doi: 10.1021/acs.inorgchem.4c04268. Online ahead of print.

Authors

Yu-Meng Zhao¹, Jie-Sheng Hu¹, Xue-Yang Ji¹, Zhi-Kun Liu¹, Ling-Tai Yue¹, Meng Yu¹, Jun Tao¹

Affiliation

¹ Key Laboratory of Cluster Science of Ministry of Education, School of Chemistry and Chemical Engineering, Liangxiang Campus, Beijing Institute of Technology, Beijing 102488, People's Republic of China.

PMID: 39526956
DOI: 10.1021/acs.inorgchem.4c04268

Abstract

A diarylethene ligand-anchored two-dimensional Hofmann-type compound [Fe^II(BTEPy){Pt(CN)₄}](CH₃OH) (BTEPy = 1,2-bis[2-methyl-5-(4-pyridyl)-3-thienyl]cyclopentene) is synthesized, which undergoes a two-step spin-state transition and dual photoinduced magnetic switching.