Effects of additives on shifting phosphorus to solid phase during Solid-Liquid separation of digestate in full-scale biogas plant

Bioresour Technol. 2024 Nov 12:416:131804. doi: 10.1016/j.biortech.2024.131804. Online ahead of print.

Abstract

Phosphorus (P) is critical for plant growth, but global reserves are exhausting within 250-300 years, therefore enhancing phosphate recycling is crucial for the future. Biogas digestate, rich with nutrients is a promising resource for nutrient recovery. Conventional solid-liquid separation shifts approximately 35 % of the total P in the digestate to the solid phase. Separation trials with additive treatment using a screw press with a 0.75 mm sieve were performed at University of Hohenheim's full-scale biogas plant. After 22 h, 67.41 % (kieserite treatment) and 52.35 % (strawflour treatment) of total P shifted to the solid phase. Treatment with kieserite enhanced P shift into the solid phase by forming non-labile fractions through a chemical bond between P and Mg2+ ions. Kieserite treatment for 22 h effectively increases the share of total P in the separated solid phase, it also ensures a sustainable nutrient supply and mitigates the risk of nutrient runoff.

Keywords: Kieserite; Non-labile-P; Nutrient recovery; Phosphorus; Screw press; Straw flour.