Fishing net-inspired PVA-chitosan-CNT hydrogels with high stretchability, sensitivity, and environmentally stability for textile strain sensors

Soft electronic products are being extensively investigated in diverse applications including sensors and devices, due to their superior softness, responsiveness, and biocompatibility. One-dimensional (1-D) fiber electronic devices are recognized for their lightweight, wearable, and stretchable qualities, thus emerging as critical constituents for seamless integration with the human body and attire, exhibiting great potential in wearable applications. However, wearable conductive hydrogel fibers usually face challenges in combining stretchability and excellent stability, notably in high-temperature environment. Herein, a novel stretchable conductive hydrogel fiber, namely PVA-CS-CNT (Polyvinyl Alcohol-Chitosan-Carbon Nanotube) hydrogel fiber, was successfully prepared through a straightforward low-temperature process. This hydrogel fiber not only maintains stable signal transmission at high temperatures but also exhibits significant mechanical and sensing capabilities, ensuring signal stability during repetitive cyclic stretching. Inspired by fishing net, textile sensors were fabricated by weaving PVA-CS-CNT hydrogel fibers, which offered breathability, high stability (withstanding over 500 stretch cycles), high sensitivity (detecting strains as low as 1 %), and exceptional mechanical strength (exceeding 17 MPa). The wearable sensor could not only accurately monitor human movements like stretching and bending, but also adeptly captured delicate signals such as pulses and sounds. These characteristics demonstrated the potential applications of the hydrogel fibers encompassing human motion tracking, intelligent textiles, and soft robotics.