On-road measurement of post-catalyst ammonia emissions from gasoline and hybrid vehicles using quantum cascade laser detector

Ammonia emissions from gasoline vehicles have been confirmed an essential precursor of urban secondary aerosols. To more comprehensively understand the formation mechanisms and better control vehicle-related ammonia, this paper measured the on-road ammonia emissions from six conventional and four hybrid vehicles using a state-of-the-art Quantum Cascade Laser analyzer on urban, rural, and highway routes. The test vehicles emitted 0.01-4.27 mg/km of ammonia emissions, with a fleet average of 1.04 mg/km. Compared to the previous laboratory tests, the results of this study were low because of the high emission standards of the vehicles and the near-zero emissions during rural driving. Most test vehicles showed high ammonia emissions during engine warm-up, while some vehicles also had ammonia peaks during dynamic highway driving. On average, hybrid vehicles emitted 60.7% less ammonia emissions than the conventional candidates. It is confirmed that ammonia was formed when incomplete oxidation products presented on a warm catalyst. Engine warm-up, dynamic highway driving, particulate filter regeneration, and hybrid engine re-starting could be important sources. It is hypothesized that the ammonia formed on the upstream catalyst could be consumed by the downstream catalyst at moderate catalyst temperature, resulting in the near-zero ammonia emissions during rural driving.