A 9R-like 2D hybrid metal halide with remarkably low melting temperature

Wei Wang; Jing-Meng Zhang; Ming-Liang Jin; Chang-Qing Jing; Wen Zhang

doi:10.1039/d4cc05616g

A 9R-like 2D hybrid metal halide with remarkably low melting temperature

Chem Commun (Camb). 2024 Dec 19;61(2):362-365. doi: 10.1039/d4cc05616g.

Authors

Wei Wang¹, Jing-Meng Zhang¹, Ming-Liang Jin¹, Chang-Qing Jing¹, Wen Zhang¹

Affiliation

¹ Jiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics and School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China. [email protected].

PMID: 39639700
DOI: 10.1039/d4cc05616g

Abstract

N-Methyl-2-hydroxy-1-ethanaminium lead iodide exhibits a low melting temperature (T_m = 99 °C) among 2D hybrid metal halides (HMHs). This discovery expands the low melting characteristics of 2D HMHs to include a stepped 9R-like structure, suggesting significant potential for melt-processing and hybrid glass formation.