Photocatalytic material-microorganism hybrid systems in water decontamination

Biological processes are widely used technologies for water decontamination, but they are often limited by insufficient bioavailable carbon sources or biorecalcitrant contaminants. The recently developed photocatalytic material-microorganism hybrid (PMH) system combines the light-harvesting capacities of photocatalytic materials with specific enzymatic activities of whole cells, efficiently achieving solar-to-chemical conversion. By integrating the benefits of both photocatalysis and biological processes, the PMH system shows great potential for water decontamination. While recent reviews have focused primarily on its application in green energy development, this review emphasizes the latest advancements in PMH systems for water decontamination, covering various applications, key considerations, and synergistic mechanisms. This review aims to provide a fundamental understanding of the PMH system and explore its broader potential in environmental remediation.