Nanoscale Indentation-Induced Crystal Plasticity in CrCoNi Medium-Entropy Alloys Containing Short-Range Order

Materials (Basel). 2024 Dec 4;17(23):5932. doi: 10.3390/ma17235932.

Abstract

CrCoNi medium-entropy alloys (MEAs), characterised by their high configurational entropies, have become a research hotspot in materials science. Recent studies have indicated that MEAs exhibit short-range order (SRO), which affects their deformation mechanisms. In this study, the micro-mechanisms of SRO within the framework of mesoscale continuum mechanics are mathematically evaluated using an advanced, non-local crystal plasticity constitutive framework. Furthermore, a crystal plasticity model considering the impact of SRO on slip is established. By combining nanoindentation simulations and multi-level grain model tensile simulations, the load-displacement and stress-strain curves demonstrated that the presence of SRO increases the hardness of MEAs. More specifically, considering the distribution of shear strain and geometrically necessary dislocations, the heterogeneity of MEAs increases with an increase in the degree of SRO. This study not only enriches the crystal plasticity theory but also provides references for the microstructure and performance regulation of high-performance multi-level grain structure materials.

Keywords: crystal plasticity; dislocation slip; geometrically necessary dislocation; medium-entropy alloy; short-range order.