Rapid and well-controlled degradation of polylactic acid materials with bio-based GEL(pectin/α-cellulose/SiO₂/CaCl₂)

Polylactic acid (PLA) has been a subject of considerable interest as a degradable polymer. However, the degradation process is slow and uncontrollable. In this work, controlled degradable PLA/bio-based GEL (pectin/α-cellulose/SiO₂/CaCl₂) hydrophilic plasticizer composite material was successfully prepared by solution blending process. The bio-based GEL was proven to have strong water absorption properties and the ability to improve and regulate the degradation performance of PLA. The results declared that the addition of 5 % GEL and 15 % polyethylene glycol (PEG) to the PLA composites resulted in a degradation degree of 83 % within 12 h in an alkaline solution. And the rate represents a 21.2-fold increase in speed compared to pure PLA material. Under neutral and acidic conditions, the degradation degree of the modified composites was approximately 169 times faster than that of pure PLA. Meanwhile, the tensile strength of PLA composites decreased from 44.8 MPa to 16.7 MPa, but the elongation at break increased from 5.8 % to 172 % compared to pure PLA. Furthermore, the initial decomposition temperature and maximum thermal decomposition rate temperature of PLA composites were found to be reduced. The controlled degradation of PLA composites was accomplished through the regulation of GEL content. The hydrolysis degradation process under different pH laid a foundation for the pretreatment process of soil microbial degradation of PLA. The mechanism suggested that the GEL created a large number of pores on the surface and inside the material within an extremely short period of time, providing ample opportunities for soil microorganisms to invade.