Water-Resistant Poly(vinyl alcohol)/ZnO Nanopillar Composite Films for Antibacterial Packaging

Yuanjian Xie; Pingxiong Cai; Xiaofeng Cao; Bo Chen; Yuanfeng Pan

doi:10.1021/acsomega.4c07173

Water-Resistant Poly(vinyl alcohol)/ZnO Nanopillar Composite Films for Antibacterial Packaging

ACS Omega. 2024 Dec 11;9(51):50403-50413. doi: 10.1021/acsomega.4c07173. eCollection 2024 Dec 24.

Authors

Yuanjian Xie¹, Pingxiong Cai¹, Xiaofeng Cao¹, Bo Chen¹, Yuanfeng Pan²

Affiliations

¹ Guangxi Key Laboratory of Green Chemical Materials and Safety Technology, Guangxi Engineering Research Center for New Chemical Materials and Safety Technology, College of Petroleum and Chemical Engineering, Beibu Gulf University, Qinzhou 535011, China.
² Guangxi Colleges and Universities Key Laboratory of New Technology and Application in Resource Chemical Engineering, School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China.

Abstract

To solve the problems that poly(vinyl alcohol) (PVA) easily breeds bacteria and swells in a humid environment, PVA and ZnO nanopillar (ZnO NP) components were composed to generate PVA/ZnO NP composite films via a simple combination process of blending and heat treatment in this study. Here, ZnO NPs endowed composite films with good antibacterial properties, and the etherification and dehydration of hydroxyl groups between PVA molecular chains induced by heat treatment resulted in the composite films having excellent water-swelling resistance. Most importantly, PVA/ZnO NP composite films revealed excellent tensile strength in both humid (52.85 MPa) and dry (74.63 MPa) environments. In addition, PVA/ZnO NP composite films showed good antibacterial and antisepsis abilities as well as preservation functions in the packaging test of half-cut apples. The current work disclosed an easy strategy for producing a PVA-based antibacterial film for packaging materials that are water-resistant and highly strong, making them suitable for applications in humid environments.