The discharge of chlorinated effluent from wastewater treatment plants enhances dissolved oxygen in the receiving river: From laboratory study to practical application

Dissolved oxygen (DO) is essential for the health of aquatic ecosystems, supporting biogeochemical cycles and the decomposition of organic matter. However, continuous untreated external inputs from illicit discharges or sewer overflows, coupled with inadequate ecological base flow, have led to widespread river deoxygenation and serious ecological crises. This study demonstrates that chlorinated wastewater treatment plant (WWTP) effluent can significantly enhance DO levels in downstream rivers, particularly in areas with high pollution loads or poor ecological base flow. Notably, DO increases in receiving waters were positively correlated with initial chorine doses. Residual chlorine in WWTP effluent reduced inorganic nitrogen and dissolved organic matter (DOM). Analysis of DOM and molecular properties showed that residual chlorine preferentially reacts with low-molecular-weight organics like amino acids, increasing their hydrophobicity and electrophilicity. These molecular changes inhibit enzyme interactions, reducing the bioavailability of these compounds for oxygen-consuming processes. Field studies demonstrated that through on-site optimization of the full-scale WWTP disinfection process, specifically by controlling residual chlorine levels in effluents, DO levels downstream increased by an average of 15 %, with a maximum of 48 % compared to upstream levels, while typical disinfection byproducts (i.e., trihalomethanes, haloacetic acids and haloacetonitriles) remained below regulatory thresholds. This work provides new insights into the positive effects of chlorinated WWTP effluent on DO levels in receiving waters.