Synergistic photocatalytic degradation of methylene blue and ibuprofen using Co₃O₄-Decorated hexagonal boron nitride (hBN) composites under Sun-like irradiation

Chemosphere. 2025 Feb:371:144061. doi: 10.1016/j.chemosphere.2025.144061. Epub 2025 Jan 8.

Abstract

In this study, we report the synthesis and photocatalytic performance of Co₃O₄-decorated hexagonal boron nitride (hBN) composites for degrading methylene blue (MB) and ibuprofen (IBF) under sunlight irradiation. Using a dry impregnation method, the composites were prepared with varying Co₃O₄ loadings (0.5%, 1%, 2%). Comprehensive characterization confirmed the successful incorporation and uniform distribution of Co₃O₄ on the hBN matrix. Photocatalytic experiments revealed that 1% Co₃O₄-hBN composite exhibited the highest activity, achieving nearly 100% MB degradation in 60 min and 90% IBF degradation in 120 min. The enhanced photocatalytic efficiency is attributed to the synergistic effects between Co₃O₄ and hBN, which extend light absorption and promote charge separation. Our findings demonstrate the potential of Co3O₄-decorated hBN composites as effective photocatalysts for environmental remediation. The study provides a foundation for further exploration of these materials, including their long-term stability and application to a broader range of pollutants.

Keywords: Co(3)O(4); Degradation; Ibuprofen; Nanocomposite; Sunlight irradiation; hBN; methylene blue.

MeSH terms

  • Boron Compounds* / chemistry
  • Catalysis
  • Cobalt* / chemistry
  • Environmental Restoration and Remediation / methods
  • Ibuprofen* / chemistry
  • Methylene Blue* / chemistry
  • Oxides / chemistry
  • Sunlight

Substances

  • Ibuprofen
  • boron nitride
  • Methylene Blue
  • Boron Compounds
  • Cobalt
  • Oxides
  • cobalt oxide