Oil recovery and heat transfer performance of polyurethane sponges coated with 3D carbon nano networks

J Hazard Mater. 2024 Dec 31:486:137045. doi: 10.1016/j.jhazmat.2024.137045. Online ahead of print.

Abstract

Heatable super hydrophobic polyurethane (PU) sponges (S-GNS/CNT/PVA@PU) containing three-dimensional (3D) carbon nano-networks (CNNs) coatings made from two-dimensional (2D) expanded graphite nano-sheets (GNS) bridged by one-dimensional (1D) carbon nano-tubes (CNT) were constructed using polyvinyl alcohol (PVA) as binder, in which light and/or electric energy could be rapidly converted into heat to reduce the viscosity of spilled heavy oils, resulting in greatly increased oil. Their heavy oil recovery rate could reach 792 kg/(m2·h) under combined light and Joule heating of 1 sun and 5 V. Surface heat dissipating coefficient Ks, heat dissipating index n, and surface heat absorption capacity Cs were studied relating to sizes and shapes of surface heating fields under varied heating modes. Deviations from Newton's law of cooling were observed, with n values varying from 1.070 to 1.690.

Keywords: Absorbent; Carbon nano network; Heat dissipation; Heavy oil recovery; Surface heating field.

Publication types

  • Letter