Bioactive Phenolics of Hyoscyamus muticus L. Subsp. Falezlez: A Molecular and Biochemical Approach to Antioxidant and Urease Inhibitory Activities

Int J Mol Sci. 2025 Jan 4;26(1):370. doi: 10.3390/ijms26010370.

Abstract

This study examines the chemical composition, antioxidant properties, and urease inhibitory effects of Hyoscyamus muticus L. subsp. falezlez (Coss.) Maire. Using LC-ESI-MS/MS, 19 distinct phenolic compounds were identified, with chlorogenic acid being the most abundant. The ethanol extract demonstrated notable antioxidant activity, highlighting its potential for therapeutic use. Urease inhibition assays revealed a remarkable 91.35% inhibition by the H. muticus extract, with an IC50 value of 5.6 ± 1.20 μg/mL, indicating its promising role in addressing conditions linked to urease activity. Molecular docking studies further investigated the interaction between H. muticus phenolic compounds and urease, identifying hyperoside as a leading candidate, with a binding energy of -7.9 kcal/mol. Other compounds, such as rutin, luteolin, apigenin, kaempferol, hesperetin, chlorogenic acid, and rosmarinic acid, also demonstrated significant binding affinities, suggesting their potential to disrupt urease function. These findings highlight the therapeutic potential of H. muticus as a source of natural bioactive compounds, offering promising avenues for the development of novel treatments for urease-related disorders and oxidative stress.

Keywords: Hyoscyamus muticus; LC-ESI-MS/MS; antioxidant activity; molecular docking; phenolic compounds; urease inhibition.

MeSH terms

  • Antioxidants* / chemistry
  • Antioxidants* / pharmacology
  • Chlorogenic Acid / chemistry
  • Chlorogenic Acid / pharmacology
  • Crassulaceae / chemistry
  • Enzyme Inhibitors / chemistry
  • Enzyme Inhibitors / pharmacology
  • Molecular Docking Simulation*
  • Phenols* / chemistry
  • Phenols* / pharmacology
  • Plant Extracts* / chemistry
  • Plant Extracts* / pharmacology
  • Urease* / antagonists & inhibitors
  • Urease* / metabolism

Substances

  • Urease
  • Phenols
  • Antioxidants
  • Plant Extracts
  • Enzyme Inhibitors
  • Chlorogenic Acid

Grants and funding

Researchers’ supporting project number (RSPD2024R710), King Saud University, Riyadh, Saudi Arabia.