Use of corn carbon as an additive to enhance magnesium metal self-corrosion and recover phosphorus from swine wastewater in the form of struvite

Environ Res. 2025 Jan 20:120865. doi: 10.1016/j.envres.2025.120865. Online ahead of print.

Abstract

Recovery of phosphate from swine wastewater is significant for alleviating eutrophication in aquatic ecosystems and addressing the increasing scarcity of phosphorus resources. In this study, a method for phosphate recovery from swine wastewater using corn carbon as an additive and non-dynamic magnesium metal self-corrosion was studied. The effects of reaction time, C:Mg mass ratio, stirring rate, and aeration rate on phosphate recovery were discussed, and eight experimental models were explored. The results demonstrated that when the optimal reaction time was 7 h, the mass ratio of corn carbon to the magnesium plate was 5:1. When the stirring rate was 800 rpm/min and the aeration rate was 0.48 m3/L·h, the pH value of wastewater was 9.24, and the phosphate recovery rate was 95.61%. The recovered precipitate was characterized by SEM-EDS and XRD as struvite with excellent crystal shape. This method not only successfully achieved waste treatment but also recovered phosphorus from swine wastewater.

Keywords: Corn carbon; Magnesium metal corrosion; Phosphorus recovery; Struvite; Treating waste with waste.